苯丙炔酸低聚物的合成及性能

极性-共轭双取代乙炔-苯丙炔酸在Pd(PPh3)2Cl2催化下直接通过易位催化机理聚合为低聚物.单体苯丙炔酸由两步制得,先通过液溴和肉桂酸的加成反应得到二溴代苯丙酸,然后消去两分子溴化氢得到单体.通过红外光谱(IR)、核磁共振(NMR)对单体及低聚物的结构进行了表征.凝胶渗透色谱(GPC)结果显示,聚合反应以甲苯作溶剂,75℃下效果最好,产率中等.这种共轭低聚物可以溶于四氢呋喃(THF)等极性溶剂,TGA结果表明低聚物热稳定性高.紫外可见吸收光谱(UV-Vis)显示,由于聚合后共轭主链大大增长,苯丙炔酸低聚物骨架上电子的跃迁使得低聚物的四氢呋喃溶液在波长高于310 nm光谱的区域中有吸收.荧光光谱(FS)显示,低聚物的四氢呋喃溶液在342 nm激发光下发蓝光,420 nm处有特征荧光发射峰.     

电容法研究卵磷脂/氨基酸/H_2O胶束和囊泡体系

运用电容法研究卵磷脂/氨基酸/H2O胶束和囊泡体系结构与性质.卵磷脂的临界胶束浓度和囊泡生成浓度可由体系电容-卵磷脂浓度关系曲线求得.随着卵磷脂浓度增加,体系电容增加,卵磷脂由胶束形成囊泡.随着氨基酸浓度增加,胶束、囊泡半径增大,体系电容减小.氨基酸能促进卵磷脂形成胶束和囊泡,使得卵磷脂临界胶束浓度和囊泡生成浓度减小,其影响的强弱顺序为组氨酸色氨酸垌甘氨酸.     

高温高压固态复分解反应法生长氮化镓的应变性质研究

本文采用高温高压下固态复分解反应法生长氮化镓.用X射线衍射仪、扫描电子显微镜、激光拉曼光谱仪对其进行分析,结果表明生成了六角纤锌矿结构的氮化镓晶体.该样品在宏观上受到了张应力的作用,退火后,宏观的应变状态由张应变向压应变转变;晶体微观应力减小,晶粒尺寸变大,晶体质量变好.     

傅里叶红外光谱仪测定地表水中的石油类

傅里叶红外光谱仪测定地表水中石油类,用一次定量萃取代替两次萃取定容,用无水硫酸钠过滤吸水代替经过硅酸镁柱.方法的精密度和准确度均达到国家标准要求,减轻了工作量,提高了分析速度,可用于日常样品地表水中石油类的监测.     

多功能夫琅禾费衍射演示仪的研制

针对目前国内夫琅禾费衍射演示仪存在的问题,研制了一种＂多功能夫琅禾费衍射演示仪＂,实现了26种衍射缝的夫琅禾费衍射的演示实验及相应的计算机（变参数）模拟仿真实验,具有演示与仿真一体化、演示种类多、演示效果明显,自动快速、使用方便、功能多样等特点,能够满足光学课程对夫琅禾费衍射进行演示实验的要求。     

LD-end-pumped 60 pm linewidth Tm:YLF laser

Narrow linewidth continuous-wave Tm:YLF laser at room temperature with a Volume Bragg grating and double Fabry-Perot etalons by using the end-pumping configuration was presented. The Tm:YLF laser operates at 1907.3 nm with FWHM of approximately 60 pm. We achieved the maximum output power of 1.92 W when the incident pump power of 13.9 W, corresponding to the optical-to-optical conversion efficiency of 13.8% and slope efficiency of 16.4%.     

Diode pumped operation of 1 mm Tm,Ho:YAP microchip laser

A single-longitudinal-mode (SLM) operation of a c-cut 1 mm Tm(5%), Ho(0.3%):YAP micro-chip laser pumped by a fiber-coupled diode-laser was reported. Under cryogenic temperature, the output power of 216 mW was obtained under the incident power of 2230 mW, corresponding to the slope efficiency was 13.6%. As much as 133 mW output and slope efficiency of 4.9% was obtained under the pump power of 3000 mW at 291 K. In addition, a maximum SLM output power of 30 mW at wavelength of 2130.56 nm is demonstrated under 77 K.     

A linear cavity multiwavelength fiber laser with adjustable lasing line number for fixed spectral regions

We report an experimental demonstration of muliwavelength erbium-doped fiber laser with adjustable wavelength number based on a power-symmetric nonlinear optical loop mirror (NOLM) in a linear cavity. The intensity-dependent loss (IDL) induced by the NOLM is used to suppress the mode competition and realize the stable multiwavelength oscillation. The controlling of the wavelength number is achieved by adjusting the strength of IDL, which is dependent on the pump power. As the pump power increases from 40 to 408 mW, 1–7 lasing line(s) at fixed wavelength around 1601 nm are obtained. The output power stability is also investigated. The most power fluctuation of single wavelength is less than 0.9 dB, when the wavelength number is increased from 1–7.     

Diode both ends pumped two crystals Tm:YLF laser

In this paper, we report two crystals Tm:YLF laser pumped by a fiber coupled diode laser with total power of 180 W at 792 nm. When the incident power reached up to 117.0 and 37.3 W of the emission wave-length at 1.91 μm was achieved. Through linear fit, the corresponding slope efficiency of 38.5%, optical-to-optical conversion efficiency of 31.9% and the beam quality factor of M ² ∼ 1.1 were obtained, indicating nearly diffraction limited beam propagation. To our best knowledge, this is the best beam quality among the reported paper results under the similar experiments.     

Room temperature diode-pumped Tm,Ho:YAP laser with double etalons

A diode end-pumped single-frequency Tm,Ho:YAP laser at room temperature was reported. We obtain a single frequency Tm,Ho:YAP laser of up to 31 mW with Fabry-Perot etalons in the cavity at 2130.8 nm. The optical conversion efficiency is 1.0% and the slope efficiency is 6.3%. The measured full width at half maximum (FWHM) is approximately 65 pm. The single-longitudinal-mode (SLM) laser can be used as a seed laser for coherent wind measurements and differential absorption LIDAR systems.